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What is Plasma?

Plasma is simply a gas (air) that the Converter ionizes so it becomes an effective electrical conductor and produces a lightning-like arc of electricity that is the source of the intense energy transferred to the waste material as radiant energy. The arc in the plasma plume within the vessel can be as high as 30,000 degrees Fahrenheit ... three times hotter than the surface of the Sun. When waste materials are subjected to the intensity of the energy transfer within the vessel, the excitation of the wastes' molecular bonds is so great that the waste materials' molecules break apart into their elemental components (atoms). It is the absorption of this energy by the waste material that forces the waste destruction and elemental dissociation.
The Plasma Converter is computer controlled, easy to use and operates at normal atmospheric pressure, very safely and quietly.

Plasma Converter System(PCS)
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How Does the System Work?

The basic Plasma Converter system consists of the following:

  • In-feed System
  • Plasma Vessel
  • Gas Polisher
  • Computer Control Station
  • Power Supply
Figure 1. Process Overview of PCS

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Feed System

The feed mechanism can simultaneously accommodate any proportion or combination of solid, liquid and gaseous feedstock. Solid wastes, depending upon their composition, can be pumped, screw fed, or ram fed into the plasma vessel. A shredder ahead of the feed system may be appropriate to achieve size reduction or object separation prior to direct system feed.

Liquid wastes, including sludge, can be pumped directly into the PCS through the wall of the plasma vessel through a special in-feed nozzle. The liquid feed system is designed to also accommodate any entrained solids that may be present. Similarly, gaseous feedstock may also be introduced into the plasma vessel through a specially designed nozzle.

Plasma Vessel

The plasma vessel is a cylindrical two-part container made of stainless steel with an opening in the roof through which the plasma torch is inserted. The vessel is lined with insulation and refractory to allow both maximum retention of internal energy and to protect the stainless steel container from the intense heat inside the vessel. The plasma vessel is equipped with inspection ports (including a video camera so the operator can see real time images inside the vessel to assist in PCS operation), openings for introduction of feedstock, and an exit port for removal of excess molten material. The smaller vessels are designed to remove molten material periodically through an automated tipping mechanism during which time the vessel may or may not remain in continuous operation. A design enhancement incorporated into the most recently constructed system is a continuous melt extraction feature which maintains the level of molten material in the plasma vessel at or below a preset limit without interrupting the operation of the system. This melt extraction system can be deployed with all sizes of Plasma Converters.

The plasma vessel is specially designed to ensure that no feedstock material is able to reach the exit port without first passing through the plasma energy field and undergoing complete molecular dissociation. The method by which this is accomplished forms a part of Startech's intellectual property. In addition, the plasma vessel is maintained at a slight negative pressure to ensure that no gases can escape to atmosphere.

The plasma torch system is a commercially available product that Startech can purchase from any number of reputable vendors. Comparable plasma systems have been used extensively in the metallurgical industry for decades. The most maintenance-intensive aspect of the PCS is the need to periodically replace electrodes, which occurs approximately every 300 to 500 hours of operation (typical). Electrode replacement can be accomplished in approximately 30 minutes thus ensuring minimum downtime of the PCS.

The PCS is also equipped with a torch positional system that allows the operator to aim the torch at different points within the plasma vessel. This aspect of the PCS allows the operator to quickly and efficiently treat feedstock as they enter the vessel and move around inside the vessel to avoid any build-up of solidified melt that may occur on the vessel walls.

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Gas Treatment System

    The gas treatment system is comprised of six stages:
  • High temperature cyclone separator to remove particulates
  • Quench stage (with heat recovery, if desired)
  • Cartridge dust collector to remove particulates
  • Selective catalytic reduction to remove NOx
  • Packed column scrubber to remove acids and volatized metals
  • Final polishing

High Temperature Cyclone Separator
The initial step of the gas treating process is a pre-quench in which the PCG is cooled from approximately 1000°C down to 650°C by direct water injection with a conventional spray dryer arrangement. The PCG then flows through a refractory lined pipe into a conventional, insulated cyclone fabricated with high temperature alloy and designed to operate at high temperatures. The purpose of the cyclone is to remove particulate matter, which is then collected and batch-fed back into the plasma vessel.

Quench
PCG then flows to a spray dryer designed to rapidly reduce the gas temperature from approximately 650°C down to 120°C. The importance of this temperature reduction is to ensure that dioxins and furans, troublesome by-products of incineration, do not form. In order for dioxins and furans to form, the gas would need to remain in a specific temperature zone (e.g., 190°C to 330°C) for some period of time - conditions which are precluded by the quench.

Cartridge Dust Collector
PCG then flows to a commercial pulsejet cartridge dust collector with high-temperature cartridges and heating elements to prevent condensation. This unit is capable of automatically "blowing back" collected solids that are collected and batch-fed back into the plasma vessel.

Selective Catalytic Reduction (SCR)
Upon exiting the dust collector, the PCG is reheated to approximately 310°C for selective catalytic reduction of NOx in a standard unit designed for this application where hydrogen present in the PCG reacts with NOx to form atmospheric nitrogen and water. During periods where there is no hydrogen in the PCG (e.g. during start-up, when processing materials that do not contain carbon), urea is added to reduce the NOx.

Packed Column Scrubber
Upon exiting the SCR, PCG undergoes a final quench with direct water injection to reduce the temperature below 50°C. This prepares the PCG for acid gas removal, which is accomplished in a standard horizontal packed column scrubber. Other inorganic species dissolve into the scrubbing liquid as common ions including chloride, fluoride, sulphate, phosphate, sodium and calcium. To manage the build-up of salts, the scrubbing solution is removed and replenished with fresh water. The wastewater typically requires no further treatment prior to discharge to sewer, except in the event there is a high concentration of heavy metals entering the system as feedstock. Approximately 75% of metals go into the melt with the remainder being volatilized and entrained in the PCG where they are captured in the scrubber and carbon filter (see below). The wastewater also contains particulates below one micron.

Finally, a standard variable speed fan at the exit of the gas treatment train pulls PCG through the entire system and maintains a constant, slight negative pressure within the plasma vessel.

The system has been designed so that it is comfortable, intuitive, and easy to use. The skill level of the operator need not be any higher than one having a reasonable technical aptitude.

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